Insights into Full-congener Profiles of Chlorinated Benzenes in Fly and Bottom Ash: Case Study in Vietnamese Industrial and Municipal Waste Incinerators.

Chlorinated benzenes (CBzs) are a group of organic pollutants, which have been industrially or unintentionally produced through various chemical and thermal processes. Studies on full congener profiles of CBzs in waste and environmental samples are relatively limited and not updated. In the present study, concentrations of 12 CBzs were determined in fly ash (FA) and bottom ash (BA) samples collected from one municipal waste incinerator (MWI) and one industrial waste incinerator (IWI) in northern Vietnam. Levels of Σ12CBzs were higher in bottom ash (median 25.3; range 1.59-45.7 ng/g) than in fly ash (median 7.30; range 1.04-30.0 ng/g). The CBz profiles were dominated by di- and tri-chlorinated congeners with the major congeners as 1,2,4-TCB, 1,2,3-TCB, 1,2-DCB, and 1,3-DCB. However, CBz profiles varied greatly between sample types and incinerators, implying differences in input materials, formation pathways, and pollutant behaviors. Incomplete combustion is possibly responsible for high levels of CBzs in industrial bottom ash. The emission factors of Σ12CBzs ranged from 21 to 600 µg/ton for fly ash and from 190 to 4570 µg/ton for bottom ash, resulting in annual emissions of about 6 and 3 g/year for the IWI and MWI, respectively. Our results suggest additional investigations on industrial emission and environmental occurrence of all 12 CBzs rather than solely focusing on regulated congeners like hexachlorobenzene and pentachlorobenzene.

Photodegradation of 2-chlorodibenzo-p-dioxin (2-CDD) on the surface of municipal solid waste incineration fly ash: Kinetics and product analysis.

Considering that waste incineration fly ash is the main carrier of dioxins and can migrate over long distances in the atmosphere, it is of great significance to study the photochemical transformation behavior of dioxins on the surface of fly ash. In this work, 2-chlorodibenzo-p-dioxin (2-CDD) was selected to conduct a systematic photochemical study. The influence of various factors on the photodegradation of 2-CDD were first explored, and the results showed that small particle size of fly ash, low concentration of 2-CDD and appropriate level of humidity were more conducive to photodegradation, with the highest degradation percentage reaching 76%-84%. The components of fly ash (Zn (Ⅱ), Al (Ⅲ), Cu (Ⅱ) and SiO2) also had a certain promoting effect on the degradation of 2-CDD, which increases the degradation efficiency by 10%-20%, because they could act as effective photocatalysts to produce free radicals for reaction. With a higher total light exposure intensity, natural light environments led to a more complete degradation of 2-CDD than laboratory Xe lamp irradiation (90% degradation Vs. 79% degradation). Based on chemical probe and radical quenching experiment, hydroxyl radical also contributed to 2-CDD photodegradation on fly ash. A total of 16 intermediate products were detected by mass spectrometry analysis, and four initial reaction pathways of 2-CDD were speculated in the process, including dechlorination, ether bond cleavage, hydroxyl substitution, and hydroxyl addition. According to the results of density functional theory calculation, the reaction channels of ether bond cleavage and •OH attack were determined. The toxicity assessment software tool (TEST) was used to assess the toxicity and bioconcentration coefficient of reaction products, and it was found that the overall toxicity of the photodegradation products was reduced. This study would provide new insights into the environmental fate of dioxins during long-range atmospheric migration process.

A comprehensive review of toxicity of coal fly ash and its leachate in the ecosystem.

Coal fly ash (CFA), a byproduct of coal combustion, is a hazardous industrial solid waste. Its excessive global production, coupled with improper disposal practices, insufficient utilization and limited awareness of its inherent hazards, poses a significant threat to both ecological environment and human health. Based on the physicochemical properties of CFA and its leachates, we elucidate the forms of CFA and potential pathways for its entry into the human body, as well as the leaching behavior, maximum tolerance and biological half-life of toxic elements present in CFA. Furthermore, we provide an overview of current strategies and methods for mitigating the leaching of these harmful elements from CFA. Moreover, we systemically summarize toxic effect of CFA on organisms across various tiers of complexity, analyze epidemiological findings concerning the human health implications resulting from CFA exposure, and delve into the biotoxicological mechanisms of CFA and its leachates at cellular and molecular levels. This review aims to enhance understanding of the potential toxicity of CFA, thereby promoting increased public awareness regarding the disposal and management of this industrial waste.

Emission characteristics and removal of heavy metals in flue gas: a case study in waste incineration and coal-fired power plants.

Heavy metal pollutants such as Hg, As, Pb, Cr, and Cd emitted from coal and waste combustion have received widespread attention. In this study, we systematically investigated the emission characteristics of heavy metals in waste incineration and coal-fired flue gases, focused on testing the removal effect of self-made cold electrode electrostatic precipitator (CE-ESP) on heavy metals in flue gas, and made a comparative analysis with the existing air pollution control devices (APCDs). Test results from waste incineration power plant showed that each APCD showed a certain effect on the removal of heavy metals in condensable particulate matter (CPM), with an average removal efficiency of bag filter was 86%, but its effect on Hg removal was slightly worse. Under the coupled field with electrified cold electrode plate operation mode, the average removal efficiency of CE-ESP on heavy metals in CPM was as high as 93%, including 76% for Hg. The removal efficiency of heavy metals (especially Hg) in CPM increased with the increase of flue gas temperature difference between inlet and outlet of CE-ESP. Test results from this coal-fired power plant showed that heavy metals were enriched in fly ash to a higher degree than in slag, the synergistic control of heavy metals in submicron particulate matter by the dust remover was not obvious, and there was a significant correlation between each heavy metal emission factor and its content in coal. Under the temperature field with non-electric cold electrode plate operation mode, the overall effect of CE-ESP on the removal of gaseous heavy metals was better than that of particulate heavy metals. Under the conventional electric field operation mode, CE-ESP was less effective in removing particulate Cr and gaseous Hg0. Under the coupled field with electrified cold electrode plate operation mode, the average removal efficiencies of CE-ESP for particulate and gaseous heavy metals were 82.37% and 76.16%, respectively.

Distribution of PCDD/Fs and PCBs at different locations in a circulating fluidised bed municipal solid waste incinerator.

This study investigates a circulating fluidised bed (CFB) incineration plant to examine the concentrations and fingerprints of polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and biphenyls (PCBs) at five locations downstream of the post-combustion zone. Sampling encompassed both flue gas and ash, spanning from the high-temperature superheater to the outlet of the baghouse filter, thus covering a wide range of flue gas temperatures. The analysis reveals a continuous increase in PCDD/F and PCB concentrations in the flue gas from the superheater to the inlet of the air pollution control system (APCS). The maximum concentrations observed were 75.8 ng/Nm3 for PCDDs, 219 ng/Nm3 for PCDFs, and 763 ng/Nm3 for PCBs. These values represent 9.14, 11.5, and 6.37 times their respective concentrations at the outlet of the high-temperature superheater. Concurrently, the levels of PCDD/Fs and dioxin-like PCBs (dl-PCBs) in the ash steadily increased along the cooling path of the flue gas within the plant. Comparing dl-PCBs to the total amount of 209 PCB congeners, it was evident that dl-PCBs exhibited a trend more akin to that of PCDD/Fs. A robust linear correlation was observed between dl-PCBs and PCDD/Fs (R2 = 0.99, p < 0.001), surpassing that between PCBs and PCDD/Fs (R2 = 0.92, p < 0.01), suggesting that dl-PCBs share closer formation pathways with PCDD/Fs. Additionally, elemental composition analysis of fly ash samples aimed to explore potential links between fly ash characteristics and PCDD/F and PCB formation. The Cl/S ratio increased from 1.58 to 5.13 with decreasing flue gas temperature. Principal component analysis (PCA) was employed to visualise the concentrations of PCDD/Fs and PCBs in the flue gas alongside elemental contents in the fly ash. With the exception of PCBs in ash, all other PCDD/Fs and PCBs in fly ash exhibited positive correlations with both carbon (C) and chlorine (Cl). Furthermore, a positive relationship between C/Cl and PCDD/Fs-PCBs in fly ash implies that fly ash serves as the primary reaction surface for dioxin generation during low-temperature heterogeneous catalytic reactions.

Optimizing nutrients from fly ash-amended soil through microbial-assisted phytoremediation using response surface methodology.

Nutrients are vital ingredients to boost plant health. The availability of nutrients is limited in fly ash (FA) waste to properly implement phytoremediation. The research explored the integration of microbes and treated wastewater irrigation in phytoremediation to provide the necessary nutrients for plant growth in fly ash-amended soils. The Box-Behnken method was used to design the experimental layout for the pot study. Response surface methodology (RSM) was applied as the optimization approach to model predictions for nutrient accumulation. The implemented pot study attained the highest morphological indicators with a plastochron index of 33.40, an absolute growth rate of 2.63 cm/day, and a leaf area of 2681.68 cm2 and attained maximum biomass of 24.91 g for the treatments that included a mid-range of the variables. The combination of FA 14.98%, microbial dose 4.07 mL, and treated wastewater as the irrigation source was found to be the optimized combination for nitrogen and phosphorus accumulation of 212.4 and 8.867 mg/L.

Concentration, speciation and risk effects of multiple environmentally sensitive trace elements in respirable fine-grained fly ash.

Respirable fine-grained fly ash (RFA) is captured very inefficiently by existing air purification devices of power plant, leading to increasing concerns regarding their migration and subsequent interaction with body due to fine particle size and its complex toxic composition. Trace elements of RFA in three groups with five different sizes between 8-13 µm were analyzed in terms of available concentration, speciation and risk effects. The concentration, pollution level and ecological risk level of elements in RFA were related to particle sizes. Chronic non-carcinogenic effect risk (NER) and carcinogenic effect risk (CER) were negatively correlated with particle size. The individual weight of exposed subjects, corresponding trace elements concentration and ingestion rate in RFA were three significant variables influencing CER. NER and CER had a tenfold exaggerated effect when calculated using total element concentration of RFA. In addition to individual differences and exposure conditions, trace element properties, speciation and available concentration were the dominant factor responsible for ecological and environmental effects of trace elements in RFA, following the order As>Ni, Mn>Cr>Pb>Cu>Zn. Results of this work highlight the effects and differences of trace elements in RFA on ecology and health, and provide a basis for further pollution control and human health warning.

Comparative toxicity of coal and coal ash: Assessing biological impacts and potential mechanisms through in vitro and in vivo testing.

BACKGROUND: Coal and coal ash present inorganic elements associated with negative impacts on environment and human health. The objective of this study was to compare the toxicity of coal and coal ash from a power plant, assess their inorganic components, and investigate the biological impacts and potential mechanisms through in vitro and in vivo testing. METHODS: Particle-Induced X-ray Emission method was used to quantify inorganic elements and the toxicity was evaluated in Caenorhabditis elegans and Daphnia magna in acute and chronic procedures. The genotoxic potential was assessed using alkaline and FPG-modified Comet assay in HepG2 cells and mutagenicity was evaluated using Salmonella/microsome assay in TA97a, TA100, and TA102 strains. RESULTS: Inorganic elements such as aluminum (Al) and chromium (Cr) were detected at higher concentrations in coal ash compared to coal. These elements were found to be associated with increased toxicity of coal ash in both Caenorhabditis elegans and Daphnia magna. Coal and coal ash did not induce gene mutations, but showed genotoxic effects in HepG2 cells, which were increased using the FPG enzyme, indicating DNA oxidative damage. CONCLUSIONS: The combined findings from bioassays using C. elegans and D. magna support the higher toxicity of coal ash, which can be attributed to its elevated levels of inorganic elements. The genotoxicity observed in HepG2 cells confirms these results. This study highlights the need for continuous monitoring in areas affected by environmental degradation caused by coal power plants. Additionally, the analysis reveals significantly higher concentrations of various inorganic elements in coal ash compared to coal, providing insight into the specific elemental composition contributing to its increased toxicity.

Study on energy use and carbon emission from manufacturing of OPC and blended cements in India.

The demand for production of cements is ever increasing to meet the infrastructure development globally. The energy and emission factors available for cements in most of the life cycle assessment (LCA) databases may not exactly suit for all the geographical locations. The main challenge in Indian scenario is the absence of database for LCA study. This study attempts to develop the energy and emission factors for the manufacturing of cements in Indian context. In the present study, five different cement manufacturing plants located in north, south, east, west and central zones of India are considered to assess the energy dissipation and carbon dioxide emission involved during the production of ordinary Portland cement (OPC). Most of the data is collected from the field, so that the energy and emission factors determined will be suitable for the zonal study. The study is then extended to assess the energy consumption and carbon dioxide emission for three blended cements, viz. Portland Pozzolan cement (PPC), Portland slag cement (PSC) and composite cement (CC) with permissible known replacement levels of fly ash, granulated blast furnace slag and both fly ash and slag, respectively. The average energy use and carbon emission is found to be on higher side in India by 15.14% and 12.64%, respectively, compared to other countries in manufacturing of cements. An average energy consumption in manufacturing of PPC, PSC and CC is found to be respectively 24.5%, 35.3% and 43.13% less compared to that of OPC. The CO2 emission intensity for OPC is found to vary between 893 and 940 kg/tonne of cement from five different zones, and an average of respectively 24.8%, 40.97% and 47.18% lower CO2 emission was observed from PPC, PSC and CC compared to OPC. From the inventory results, CC has proven to be a more sustainable cement with low energy consumption and lower CO2 emission compared to other cements.

Stabilization/solidification of heavy metal-contaminated marl soil using a binary system of cement and fuel fly ash.

The stabilization/solidification (S/S) method is one of the most effective remediation techniques for treating contaminated soils. Several stabilizers, mostly the cementitious materials, have been used for the S/S treatment. In this paper, the feasibility of utilizing fuel fly ash (FFA) as a partial replacement of ordinary Portland cement (OPC) for the S/S treatment of marl soil contaminated with heavy metals was investigated. Two industrial waste materials, namely steel and electroplating wastes, were used to synthetically contaminate the marl soil. The stabilizers comprising of OPC and FFA were mixed with the contaminated soil at different dosages ranging from 10 to 40%, by mass, and a total of 48 S/S-treated soil mixtures were prepared. A series of experiments, including density, porosity, permeability, unconfined compressive strength (UCS), and toxicity characteristics leaching procedure (TCLP), were carried out on the soil mixtures to evaluate the efficiency of the proposed S/S treatment. Test results showed that the incorporation of FFA at higher volumes reduced the density and increased the porosity and permeability of the treated mixtures. Although FFA addition resulted in reducing the UCS values by an average of 46%, and this reduction was more significant at higher FFA percentages, the UCS values of all mixtures were more than 0.35 MPa (350 kPa), which passed the minimum requirements set by USEPA. In addition, the metal immobilization ability of the proposed treatment was confirmed by the TCLP analysis. As compared to the negative effect of the contamination of the soil by the electroplating waste, the contamination of the soil by steel waste had a higher negative effect. The results of this study would contribute in selecting an environment-friendly treatment of the contaminated soils using industrial waste materials, such as FFA, as a partial replacement of OPC. Nevertheless, the present study is an initial attempt to explore the possibility of utilizing FFA as a partial replacement of OPC in S/S treatment of marl soil contaminated with heavy metals. It is recommended to conduct another study in future including analysis of the treated soil mixtures using XRD, SEM, and FTIR techniques to better understand the stabilization/solidification mechanism and its implications on the test results.

Evaluation of potential radiological hazards of unfired construction materials containing fly ash in Vietnam.

In this study, the specific activities of 226Ra, 232Th and 40K in the unfired construction materials (solid card bricks, 4-hole bricks, pavement bricks) containing fly ash and bottom ash from a coal-fired thermal power plant in Vietnam were measured using the low-level gamma-ray spectrometer with HPGe detector. Also, the 222Rn concentrations in these materials were analyzed using RAD7 radon monitor and then radon mass exhalation rate and emanation fraction of these materials were calculated. The potential radiological hazards for residents living in the model room made of these materials were evaluated. The average specific activity of 226Ra, 232Th and 40K were found as 67.7, 79.3 and 703.5 Bq kg-1, respectively. The total annual effective dose (due to external gamma exposure and internal radon exposure for resident living in the CEN model room made of the unfired brick samples) was found as 0.9 mSv y-1 which is lower than the worldwide average dose of 2.4 mSv y-1. Calculations from ResRad-Build code showed that the doses due to radon exposure account for from 62.3% (at the first year) to 98.8% (at the next 30 years) of the total gamma and radon dose. Under low air exchange to the outside environment, from the 6th year onwards, the total dose may exceed the average dose value from natural radiation exposure sources.

Assessing the presence, concentration, and impacts of trace element contamination in a Chesapeake Bay tributary adjacent to a coal ash landfill (Possum Point, VA).

Coal ash (CA) is an industrial waste product that has been shown to contain several neurotoxic constituents such as cadmium, selenium, mercury, lead, and arsenic. Contaminant-laced leachates enter the environment via seepage, runoff, permitted discharge, or accidental spills from CA storage ponds or landfills which may pose a risk to wildlife residing in receiving waterways. In this study, we assessed 1) the presence and concentration of thirteen trace elements (Al, Ca, Mg, Cr, Cd, As, Se, Pb, Cu, Zn, Mn, Fe, B) in surface water and sediment grab samples using ICP-OES, 2) the temporal variability of trace elements using Pb-210 dated sediment core samples, 3) differences in species diversity using environmental DNA (eDNA) analyses, and 4) the presence and concentration of trace metals in banded killifish (Fundulus diaphanus) epaxial muscle tissue collected from waterways surrounding the Possum Point Power Station (Stafford, VA). Results showed the highest concentrations of As, Cd, Cr, Cu, Fe, Mg, Se, Zn, and B in Quantico Creek (QC) adjacent to the coal ash ponds and elevated average cadmium and zinc concentrations compared to both upstream and downstream locations along the Potomac River. Sediment core profiles and Pb-210 analyses showed historical enrichment of several trace elements in QC beginning after the commissioning of the power plant in 1948. When compared to upstream and downstream sites, species diversity was drastically reduced in Quantico Creek based on eDNA identification. Muscle tissues of banded killifish collected in Quantico Creek displayed increased Al, Cd, and Zn concentrations compared to upstream and downstream sites. Collectively, our results demonstrate the potential impacts of coal ash landfills on aquatic ecosystems and suggest that further research is needed to fully inform risk assessment and remediation efforts.

Distribution and impacts of contamination by natural and artificial radionuclides in attic dust and urban soil samples from a former industrial Hungarian city: A case study from Salgótarján.

Primordial radionuclides can be found in all environmental compartments. Since coal-fired power plants (CFPP) can be a source of additional radionuclide contamination because coal contains natural radioactive isotopes such as 238U (226Ra) and 232Th. This study investigated the impact of such possible radionuclide contamination from former heavy industrial activities, namely a former local coal-fired power plant, in urban soils and attic dust in Salgótarján, Hungary. Even today, industrial by-products, e.g., coal ash, in this city represent significant threat to its residents. A total of 36 attic dust samples (family houses, kindergartens, churches and blockhouses) were collected and 19 urban soil samples (playgrounds, kindergartens, parks and others) were selected no further than 500 m from the corresponding attic dust sampling sites. Additionally, a coal ash and a brown forest soil sample were also collected to differentiate between the anthropogenic and geogenic sources in the residential area. The sampled houses, built between 1890 and 1990, are considered to be representative sampling sites for long-term accumulations of attic dust. The mean values of the total U, Th and Cs (mg kg-1) concentrations as well as those of K (m/m %) in attic dust and urban soil samples are 2.4, 3.6, 1.7 and 0.6 and 1.1, 4.4, 1.2 and 0.3, respectively, measured using ICP-MS. The mean activity concentrations of 226Ra, 232Th, 40K and 137Cs in attic dust and urban soil samples are 43.3, 34.0, 534.4 and 88.5 and 25.1, 32.8, 386.4 and 5.6 Bq kg-1, respectively, by using a low-background iron chamber with a well-type HPGe and a n-type coaxial HPGe detector. The elemental compositions (U, Th) and activity concentrations (226Ra, 232Th) along with their abundances in coal ash from the CFPP increase in both studied media as the distance of the sampling sites from the CFPP decreases. Two outlier attic dust samples in particular show significantly high activity concentrations of 226Ra: 145 and 143, of 232Th: 83 and 94 Bq kg-1, which can be considered as a proxy of unweathered coal ash. The calculated total absorbed gamma dose rate (D) and annual effective dose (E) received from urban soils indicate that the presence of the CFPP, coal ash cone and slag dumps does not cause an increase in the level of background radiation in Salgótarján. However, the concentrations of the studied radionuclides are much higher (except for 232Th) and exhibit higher degree of variability in the samples of attic dustthan in those of urban soils. The study suggests that attic dust preserves the undisturbed 'fingerprints' of long-term atmospheric deposition thanks to its chemical and physical properties unlike urban soil.

Study on mechanical properties of coal gangue and fly ash mixture as backfill material based on fractal characteristics.

Backfill mining can effectively alleviate the problems of surface collapse and ecological water pollution, in which the mechanical properties of backfill materials, including coal gangue and coal fly ash, have a decisive role in the effect of filling mining. In this study, we analyze the permeability characteristics of coal gangue filler through a set of homemade percolation test systems and introduce fractal characteristics to investigate the key factors affecting percolation in complex pores of broken coal gangue. The results indicate that the fractal dimensions of crushed coal gangue particles show an increasing trend with increasing axial loading and that the variation range is from 2.15647 to 2.58933. The coal fly ash concentration has a positive relationship with the acceleration factor. The permeability of crushed coal gangue follows a hierarchical distribution law and the permeability changes in the magnitude range of 10-11 ~ 10-9 m2. The fractal dimension is inversely related to the permeability of crushed coal gangue. The experimental results show that the coal gangue will be further crushed and that adding a certain concentration of coal fly ash can achieve a better water barrier, which provides theoretical support and engineering significance for the stability analysis of geological engineering and backfill mining technology.

Pond ash as a potential material for sustainable geotechnical applications - a review.

Energy-harnessing sources significantly influence a country's infrastructure and economic development. Though nuclear and hydel power sources are used for energy harnessing, thermal sources are still the primary power source in India and contribute to 75% of the demand. Thermal power plants exploit large volumes of coal reserves. The combustion of coal leads to 30%-40% of waste ash residues such as Fly ash and Bottom ash. Though Fly ash finds greater applicability, pond ash poses a severe environmental hazard due to its large occupancy of terrain in ash dykes and lagoons. Many research efforts are underway to utilize pond ash in various structural and geotechnical infrastructure projects; however, there are still limitations and apprehensions about its properties and determination. The present study provides a detailed review of the morphological and chemical properties. Further, the geotechnical attributes of pond ash, including strength characteristics, consolidation parameters, and durability aspects, are critically reviewed for the probable application as fill material for backfill and many other applications. Based on the earlier research on pond ash, it could be comprehended that pond ash has wide property variability and finds compatibility with many other pozzolanic admixtures and, in this way, finds broader applicability in geotechnical projects. The way forwards could be a significant step towards cleaner and greener technology.

Examining the residual radiological footprint of a former colliery: An industrial nuclear archaeology investigation.

Nuclear industrial archaeology utilises radiation mapping and characterisation technologies to gain an insight into the radiological footprint of industrial heritage sites. Increased concentrations of naturally occurring radioactive materials at legacy mine sites are the result of elemental enrichment during coal mining and subsequent combustion. Public safety is of concern around these sites, and therefore, an increased understanding of their associated hazard is essential. Using coincident laser scanning and gamma detection technologies, this study sought to assess the radiological legacy of a coal mine located in Bristol, UK. From this, we can increase our understanding of the residual footprints associated with the local coal mining industry. Samples taken from inside the site were characterised using high resolution gamma spectrometry, wherein the radionuclide content and activities of samples were then quantified. An area of elevated low-level radioactivity was observed at and around buildings believed to belong to the colliery, while Th, U, and K are confirmed at the site from photopeak's of daughter radionuclides. Activities of the radionuclides K-40, U-238, and Th-232 were further quantified during subsequent laboratory analysis. Results highlight an enrichment of naturally occurring radionuclides when compared with global averages for unburned coal. Employing these techniques at further legacy sites would enable an increased understanding of the lasting traces of the coal mining industry, with a focus on NORM enrichment in residual fly ash.

Ecological risk assessment of heavy metals in bottom ashes generated by small-scale thermal treatment furnaces for domestic waste in villages and towns of China.

Small-scale Solid Waste Thermal Treatment (SSWTT) is prevalent in remote Chinese locations. However, the ecological threats associated with heavy metals in resultant bottom ash remain undefined. This research study scrutinized such ash from eight differing sites, assessing heavy metal content, chemical form, and leaching toxicity. Most bottom ash samples met soil contamination standards for development land (GB36600-2018). However, levels of As, Cd, Cr, Cu, Ni, Pb, and Zn in some samples exceeded agricultural land standards GB15618-2018) by 1591%, 64,478%, 1880%, 3886%, 963%, 1110%, and 2011% respectively. Additionally, the As and Cd contents surpassed the construction land control limit value by 383% and 13% respectively. The mean values of the combined oxidizable and residual fraction (F3 + F4) for each heavy metal in all samples exceeded 65%, with Cr, Cu, Ni, and Pb reaching over 95%. All sample leaching concentrations, obtained via the HJ/T 299 procedure, were less than limits set by the identification standards for hazardous wastes (GB5085.3-2007). However, only the leaching concentrations of three samples via the leaching procedure HJ/T 300 met the "Solid Waste Landfill Pollution Control Standard" (GB 16889-2008). The results indicate that the location and type of SSWTT equipment play a crucial role in determining an appropriate solution for bottom ash management.

Coal fly ash application as an eco-friendly approach for modulating the growth, yield, and biochemical constituents of Withania somnifera L. plants.

The solid waste known as fly ash, which is produced when coal is burned in thermal power plants, is sustainably used in agriculture. It is an excellent soil supplement for plant growth and development since it contains some desired nutrients (macro and micro), as well as being porous. The present study was done to evaluate the effect of different fly ash levels on Withania somnifera. The present study aimed to assess the impact of various fly ash (FA) concentrations on growth, yield, photosynthetic pigments, biochemical parameters, and cell viability of W. somnifera. The results showed that FA enhanced physical and chemical properties of soil like pH, electric conductivity, porosity, water-holding capacity, and nutrients. The low doses of FA-amended soil (15%) significantly increased the shoot length (36%), root length (24.5%), fresh weight of shoots and roots (107.8 and 50.6%), dry weight of shoots and roots (61.9 and 47.1%), number of fruits (70.4%), carotenoid (43%), total chlorophyll (44.3%), relative water content (109.3%), protein content (20.4%), proline content (110.3%), total phenols (116.1%), nitrogen (20.3%), phosphorus (16.9%), and potassium (26.4%). On the other hand, the higher doses, i.e., 25% of fly ash showed a negative effect on all the above parameters and induced oxidative stress by increasing lipid peroxidation (33.1%) and hydrogen peroxide (102.0%) and improving the activities of antioxidant enzymes and osmolytes. Compared to the control plants, the plants growing in soil enriched with 15 and 25% fly ash had larger stomata pores when examined using a scanning electron microscope. In addition, according to a confocal microscopic analysis of the roots of W. somnifera, higher fly ash concentrations caused membrane damage, as evidenced by an increase in the number of stained nuclei. Moreover, several functional groups and peaks of the biomolecules represented in the control and 15% of fly ash were alcohols, phenols, allenes, ketenes, isocynates, and hydrocarbons. Gas chromatography-mass spectrometry analysis of the methanol extract of W. somnifera leaves cultivated in soil amended with 15% fly ash shows the presence of 47 bioactive compounds. The most abundant compounds in the methanol extract were cis-9-hexadecenal (22.33%), n-hexadecanoic acid (9.68%), cinnamic acid (6.37%), glycidyl oleate (3.88%), nonanoic acid (3.48%), and pyranone (3.57%). The lower concentrations of FA (15%) can be used to enhance plant growth and lower the accumulation of FA that results in environmental pollution.

Mechanism of bonding, surface property, electrical behaviour, and environmental friendliness of carbon/ceramic composites produced via the pyrolysis of coal waste with polysiloxane polymer.

A simple mixing-pressing followed by thermal curing and pyrolysis process was used to upcycle coal waste into high-value composites. Three coal wastes of different physicochemical properties were investigated. The hypothetical mechanisms of bonding between the coal particles and the preceramic polymer are presented. The textural properties of the coals indicated that the lowest volatile coal waste (PCD) had a dense structure. This limited the diffusion and reaction of the preceramic polymer with the coal waste during pyrolysis, thereby leading to low-quality composites. The water contact angles of the composites up to 104° imply hydrophobic surfaces, hence, no external coating might be required. Analysis of the carbon phase confirmed that the amorphous carbon structure is prevalent in the composites compared to the coal wastes. The dc volume resistivity of the composites in the range of 22 to 82 Ω-cm infers that the composites are unlikely to suffer electrostatic discharge, which makes them useful in creating self-heating building parts. The leached concentrations of heavy metal elements from the composites based on the end-of-life scenario were below the Toxicity Characteristic Leaching Procedure regulatory limits. Additionally, the release potential or mobility of the metals from the composites was not influenced by the pH of the eluants used. On the basis of the reported results, these carbon/ceramic composites show tremendous prospects as building materials due to these properties.

Acid gas emission and ash fusion characteristics of multi-component leather solid waste incineration in bubbling fluidized bed.

The tanning sludge (TS) and other tanning solid wastes are produced in significant quantities by the leather industry. To evaluate the combustion properties, acid gaseous pollutant conversion, and ash management, co-firing of TS with various wastes was investigated in a bubbling fluidized bed. TG-FTIR test indicated that tanning solid wastes had superior combustion properties and include more gaseous pollutants than TS. The leather mixed solid waste (LMSW) formed by mixing had better fuel characteristics than TS. The conversion rates of SO2 and HCl of LMSW incineration were 67% and 40%, respectively. The co-combustion of TS and solid wastes reduces the conversion rate of acid gas. Increasing the proportion of high-inorganic chlorine raw material could further reduce the conversion rate and increase the ash fusion temperature appropriately. Because ash and slag were primarily composed of Ca and Fe elements, the addition of calcium carbonate (CaCO3) can increase ash melting point while reducing acid gas emissions. When CaCO3 was added at a calcium to sulfur (Ca/S) ratio of 2, the acid gas emission was reduced by more than 80% and the softening temperature was raised by 90 °C. When Ca/S is greater than 2, the economics of adding CaCO3 decreased.